1 |
|
---|
2 | MPQC: Massively Parallel Quantum Chemistry
|
---|
3 | Version 2.1.0-alpha-gcc3
|
---|
4 |
|
---|
5 | Machine: i686-pc-linux-gnu
|
---|
6 | User: cljanss@aros.ca.sandia.gov
|
---|
7 | Start Time: Sat Apr 6 14:06:51 2002
|
---|
8 |
|
---|
9 | Using ProcMessageGrp for message passing (number of nodes = 1).
|
---|
10 | Using PthreadThreadGrp for threading (number of threads = 2).
|
---|
11 | Using ProcMemoryGrp for distributed shared memory.
|
---|
12 | Total number of processors = 2
|
---|
13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
|
---|
14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-311gSS.kv.
|
---|
15 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
|
---|
16 |
|
---|
17 | USCF::init: total charge = 0
|
---|
18 |
|
---|
19 | Starting from core Hamiltonian guess
|
---|
20 |
|
---|
21 | Using symmetric orthogonalization.
|
---|
22 | n(SO): 4 0 1 2
|
---|
23 | Maximum orthogonalization residual = 1.94235
|
---|
24 | Minimum orthogonalization residual = 0.275215
|
---|
25 | alpha = [ 3 0 1 1 ]
|
---|
26 | beta = [ 2 0 0 1 ]
|
---|
27 |
|
---|
28 | USCF::init: total charge = 0
|
---|
29 |
|
---|
30 | Projecting guess wavefunction into the present basis set
|
---|
31 |
|
---|
32 | SCF::compute: energy accuracy = 1.0000000e-06
|
---|
33 |
|
---|
34 | nuclear repulsion energy = 6.0605491858
|
---|
35 |
|
---|
36 | iter 1 energy = -38.1820699187 delta = 5.64824e-01
|
---|
37 | iter 2 energy = -38.4003011385 delta = 1.24674e-01
|
---|
38 | iter 3 energy = -38.4180544451 delta = 4.28738e-02
|
---|
39 | iter 4 energy = -38.4207818964 delta = 1.77645e-02
|
---|
40 | iter 5 energy = -38.4210039537 delta = 4.15403e-03
|
---|
41 | iter 6 energy = -38.4210309242 delta = 1.17802e-03
|
---|
42 | iter 7 energy = -38.4210325834 delta = 2.78023e-04
|
---|
43 | iter 8 energy = -38.4210326590 delta = 6.34829e-05
|
---|
44 | iter 9 energy = -38.4210326633 delta = 1.34588e-05
|
---|
45 | iter 10 energy = -38.4210326648 delta = 5.94892e-06
|
---|
46 | iter 11 energy = -38.4210326652 delta = 3.49557e-06
|
---|
47 |
|
---|
48 | <S^2>exact = 2.000000
|
---|
49 | <S^2> = 2.004930
|
---|
50 |
|
---|
51 | total scf energy = -38.4210326652
|
---|
52 |
|
---|
53 | Projecting the guess density.
|
---|
54 |
|
---|
55 | The number of electrons in the guess density = 5
|
---|
56 | Using symmetric orthogonalization.
|
---|
57 | n(SO): 14 2 5 9
|
---|
58 | Maximum orthogonalization residual = 4.53967
|
---|
59 | Minimum orthogonalization residual = 0.0225907
|
---|
60 | The number of electrons in the projected density = 4.99687
|
---|
61 |
|
---|
62 | Projecting the guess density.
|
---|
63 |
|
---|
64 | The number of electrons in the guess density = 3
|
---|
65 | The number of electrons in the projected density = 2.99893
|
---|
66 |
|
---|
67 | alpha = [ 3 0 1 1 ]
|
---|
68 | beta = [ 2 0 0 1 ]
|
---|
69 |
|
---|
70 | Molecular formula CH2
|
---|
71 |
|
---|
72 | MPQC options:
|
---|
73 | matrixkit = <ReplSCMatrixKit>
|
---|
74 | filename = methods_uhf
|
---|
75 | restart_file = methods_uhf.ckpt
|
---|
76 | restart = yes
|
---|
77 | checkpoint = no
|
---|
78 | savestate = no
|
---|
79 | do_energy = yes
|
---|
80 | do_gradient = yes
|
---|
81 | optimize = no
|
---|
82 | write_pdb = no
|
---|
83 | print_mole = yes
|
---|
84 | print_timings = yes
|
---|
85 |
|
---|
86 | SCF::compute: energy accuracy = 1.0000000e-08
|
---|
87 |
|
---|
88 | nuclear repulsion energy = 6.0605491858
|
---|
89 |
|
---|
90 | iter 1 energy = -38.8416449102 delta = 7.15245e-02
|
---|
91 | iter 2 energy = -38.9052377135 delta = 1.28891e-02
|
---|
92 | iter 3 energy = -38.9137984705 delta = 4.68809e-03
|
---|
93 | iter 4 energy = -38.9158161956 delta = 2.37386e-03
|
---|
94 | iter 5 energy = -38.9162523520 delta = 1.14588e-03
|
---|
95 | iter 6 energy = -38.9163146659 delta = 4.22393e-04
|
---|
96 | iter 7 energy = -38.9163259670 delta = 1.67816e-04
|
---|
97 | iter 8 energy = -38.9163280103 delta = 5.12865e-05
|
---|
98 | iter 9 energy = -38.9163284951 delta = 1.68281e-05
|
---|
99 | iter 10 energy = -38.9163286745 delta = 1.01725e-05
|
---|
100 | iter 11 energy = -38.9163286825 delta = 7.45963e-06
|
---|
101 | iter 12 energy = -38.9163286853 delta = 1.76114e-06
|
---|
102 | iter 13 energy = -38.9163286853 delta = 5.04698e-07
|
---|
103 | iter 14 energy = -38.9163286853 delta = 2.70289e-07
|
---|
104 | iter 15 energy = -38.9163286861 delta = 5.52618e-07
|
---|
105 | iter 16 energy = -38.9163286863 delta = 4.21174e-07
|
---|
106 | iter 17 energy = -38.9163286863 delta = 2.15410e-07
|
---|
107 | iter 18 energy = -38.9163286863 delta = 9.00776e-08
|
---|
108 | iter 19 energy = -38.9163286863 delta = 2.47094e-08
|
---|
109 |
|
---|
110 | <S^2>exact = 2.000000
|
---|
111 | <S^2> = 2.005842
|
---|
112 |
|
---|
113 | total scf energy = -38.9163286863
|
---|
114 |
|
---|
115 | SCF::compute: gradient accuracy = 1.0000000e-06
|
---|
116 |
|
---|
117 | Total Gradient:
|
---|
118 | 1 C 0.0000000000 -0.0000000000 -0.0697591562
|
---|
119 | 2 H -0.0000000000 -0.0108178568 0.0348795781
|
---|
120 | 3 H -0.0000000000 0.0108178568 0.0348795781
|
---|
121 |
|
---|
122 | Value of the MolecularEnergy: -38.9163286863
|
---|
123 |
|
---|
124 |
|
---|
125 | Gradient of the MolecularEnergy:
|
---|
126 | 1 0.0000000000
|
---|
127 | 2 -0.0000000000
|
---|
128 | 3 -0.0697591562
|
---|
129 | 4 -0.0000000000
|
---|
130 | 5 -0.0108178568
|
---|
131 | 6 0.0348795781
|
---|
132 | 7 -0.0000000000
|
---|
133 | 8 0.0108178568
|
---|
134 | 9 0.0348795781
|
---|
135 |
|
---|
136 | Function Parameters:
|
---|
137 | value_accuracy = 8.741260e-09 (1.000000e-08) (computed)
|
---|
138 | gradient_accuracy = 8.741260e-07 (1.000000e-06) (computed)
|
---|
139 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
140 |
|
---|
141 | Molecule:
|
---|
142 | Molecular formula: CH2
|
---|
143 | molecule<Molecule>: (
|
---|
144 | symmetry = c2v
|
---|
145 | unit = "angstrom"
|
---|
146 | { n atoms geometry }={
|
---|
147 | 1 C [ 0.0000000000 0.0000000000 -0.1000000000]
|
---|
148 | 2 H [ -0.0000000000 0.8570000000 0.5960000000]
|
---|
149 | 3 H [ -0.0000000000 -0.8570000000 0.5960000000]
|
---|
150 | }
|
---|
151 | )
|
---|
152 | Atomic Masses:
|
---|
153 | 12.00000 1.00783 1.00783
|
---|
154 |
|
---|
155 | GaussianBasisSet:
|
---|
156 | nbasis = 30
|
---|
157 | nshell = 13
|
---|
158 | nprim = 24
|
---|
159 | name = "6-311G**"
|
---|
160 | SCF Parameters:
|
---|
161 | maxiter = 100
|
---|
162 | density_reset_frequency = 10
|
---|
163 | level_shift = 0.250000
|
---|
164 |
|
---|
165 | UnrestrictedSCF Parameters:
|
---|
166 | charge = 0.0000000000
|
---|
167 | nalpha = 5
|
---|
168 | nbeta = 3
|
---|
169 | alpha = [ 3 0 1 1 ]
|
---|
170 | beta = [ 2 0 0 1 ]
|
---|
171 |
|
---|
172 | CPU Wall
|
---|
173 | mpqc: 1.17 1.21
|
---|
174 | calc: 0.87 0.93
|
---|
175 | compute gradient: 0.22 0.25
|
---|
176 | nuc rep: 0.00 0.00
|
---|
177 | one electron gradient: 0.03 0.03
|
---|
178 | overlap gradient: 0.01 0.01
|
---|
179 | two electron gradient: 0.18 0.21
|
---|
180 | vector: 0.65 0.67
|
---|
181 | density: 0.00 0.01
|
---|
182 | evals: 0.05 0.04
|
---|
183 | extrap: 0.06 0.05
|
---|
184 | fock: 0.52 0.55
|
---|
185 | start thread: 0.19 0.19
|
---|
186 | stop thread: 0.00 0.02
|
---|
187 | input: 0.29 0.28
|
---|
188 | vector: 0.10 0.10
|
---|
189 | density: 0.01 0.01
|
---|
190 | evals: 0.01 0.01
|
---|
191 | extrap: 0.02 0.02
|
---|
192 | fock: 0.05 0.06
|
---|
193 | start thread: 0.00 0.00
|
---|
194 | stop thread: 0.00 0.00
|
---|
195 |
|
---|
196 | End Time: Sat Apr 6 14:06:53 2002
|
---|
197 |
|
---|