1 |
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2 | MPQC: Massively Parallel Quantum Chemistry
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3 | Version 2.1.0-alpha-gcc3
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4 |
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5 | Machine: i686-pc-linux-gnu
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6 | User: cljanss@aros.ca.sandia.gov
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7 | Start Time: Sat Apr 6 14:03:53 2002
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8 |
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9 | Using ProcMessageGrp for message passing (number of nodes = 1).
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10 | Using PthreadThreadGrp for threading (number of threads = 2).
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11 | Using ProcMemoryGrp for distributed shared memory.
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12 | Total number of processors = 2
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13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-311gSS.kv.
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15 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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16 |
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17 | CLSCF::init: total charge = 0
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18 |
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19 | Starting from core Hamiltonian guess
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20 |
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21 | Using symmetric orthogonalization.
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22 | n(SO): 4 0 2 1
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23 | Maximum orthogonalization residual = 1.91709
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24 | Minimum orthogonalization residual = 0.341238
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25 | docc = [ 3 0 1 1 ]
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26 | nbasis = 7
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27 |
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28 | CLSCF::init: total charge = 0
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29 |
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30 | Projecting guess wavefunction into the present basis set
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31 |
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32 | SCF::compute: energy accuracy = 1.0000000e-06
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33 |
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34 | integral intermediate storage = 31876 bytes
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35 | integral cache = 7967676 bytes
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36 | nuclear repulsion energy = 9.2104861547
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37 |
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38 | 565 integrals
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39 | iter 1 energy = -74.6502873692 delta = 7.46840e-01
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40 | 565 integrals
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41 | iter 2 energy = -74.9396377448 delta = 2.26644e-01
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42 | 565 integrals
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43 | iter 3 energy = -74.9587707069 delta = 6.77230e-02
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44 | 565 integrals
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45 | iter 4 energy = -74.9598296477 delta = 1.97077e-02
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46 | 565 integrals
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47 | iter 5 energy = -74.9598805126 delta = 4.60729e-03
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48 | 565 integrals
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49 | iter 6 energy = -74.9598807963 delta = 3.15131e-04
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50 | 565 integrals
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51 | iter 7 energy = -74.9598807973 delta = 2.01451e-05
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52 |
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53 | HOMO is 1 B2 = -0.387218
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54 | LUMO is 4 A1 = 0.598273
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55 |
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56 | total scf energy = -74.9598807973
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57 |
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58 | Projecting the guess density.
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59 |
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60 | The number of electrons in the guess density = 10
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61 | Using symmetric orthogonalization.
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62 | n(SO): 14 2 9 5
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63 | Maximum orthogonalization residual = 4.47996
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64 | Minimum orthogonalization residual = 0.0185137
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65 | The number of electrons in the projected density = 9.99141
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66 |
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67 | docc = [ 3 0 1 1 ]
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68 | nbasis = 30
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69 |
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70 | Molecular formula H2O
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71 |
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72 | MPQC options:
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73 | matrixkit = <ReplSCMatrixKit>
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74 | filename = methods_clks_lsdax
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75 | restart_file = methods_clks_lsdax.ckpt
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76 | restart = yes
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77 | checkpoint = no
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78 | savestate = no
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79 | do_energy = yes
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80 | do_gradient = yes
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81 | optimize = no
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82 | write_pdb = no
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83 | print_mole = yes
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84 | print_timings = yes
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85 |
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86 | SCF::compute: energy accuracy = 1.0000000e-08
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87 |
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88 | Initializing ShellExtent
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89 | nshell = 13
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90 | ncell = 54760
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91 | ave nsh/cell = 1.57949
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92 | max nsh/cell = 13
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93 | integral intermediate storage = 260598 bytes
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94 | integral cache = 15731962 bytes
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95 | nuclear repulsion energy = 9.2104861547
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96 |
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97 | Total integration points = 4049
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98 | Integrated electron density error = -0.000245176044
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99 | iter 1 energy = -74.8308521799 delta = 9.87174e-02
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100 | Total integration points = 11317
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101 | Integrated electron density error = -0.000003149062
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102 | iter 2 energy = -75.1942166389 delta = 5.22679e-02
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103 | Total integration points = 11317
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104 | Integrated electron density error = -0.000012627139
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105 | iter 3 energy = -75.1644088323 delta = 1.98141e-02
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106 | Total integration points = 11317
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107 | Integrated electron density error = -0.000007333794
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108 | iter 4 energy = -75.2189545619 delta = 1.10224e-02
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109 | Total integration points = 46071
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110 | Integrated electron density error = 0.000000604512
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111 | iter 5 energy = -75.2191475775 delta = 6.14679e-04
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112 | Total integration points = 46071
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113 | Integrated electron density error = 0.000000604391
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114 | iter 6 energy = -75.2191570220 delta = 1.48980e-04
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115 | Total integration points = 46071
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116 | Integrated electron density error = 0.000000604277
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117 | iter 7 energy = -75.2191571413 delta = 1.63231e-05
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118 | Total integration points = 46071
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119 | Integrated electron density error = 0.000000604286
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120 | iter 8 energy = -75.2191571432 delta = 2.36536e-06
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121 | Total integration points = 46071
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122 | Integrated electron density error = 0.000000604285
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123 | iter 9 energy = -75.2191571432 delta = 2.92686e-07
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124 | Total integration points = 46071
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125 | Integrated electron density error = 0.000000604285
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126 | iter 10 energy = -75.2191571432 delta = 1.28847e-08
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127 |
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128 | HOMO is 1 B2 = -0.188974
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129 | LUMO is 4 A1 = 0.046423
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130 |
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131 | total scf energy = -75.2191571432
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132 |
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133 | SCF::compute: gradient accuracy = 1.0000000e-06
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134 |
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135 | Initializing ShellExtent
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136 | nshell = 13
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137 | ncell = 54760
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138 | ave nsh/cell = 1.57949
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139 | max nsh/cell = 13
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140 | Total integration points = 46071
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141 | Integrated electron density error = 0.000000604546
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142 | Total Gradient:
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143 | 1 O -0.0000000000 0.0000000000 -0.0415476754
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144 | 2 H -0.0172468148 0.0000000000 0.0207738377
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145 | 3 H 0.0172468148 -0.0000000000 0.0207738377
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146 |
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147 | Value of the MolecularEnergy: -75.2191571432
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148 |
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149 |
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150 | Gradient of the MolecularEnergy:
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151 | 1 -0.0000000000
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152 | 2 0.0000000000
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153 | 3 -0.0415476754
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154 | 4 -0.0172468148
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155 | 5 0.0000000000
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156 | 6 0.0207738377
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157 | 7 0.0172468148
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158 | 8 -0.0000000000
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159 | 9 0.0207738377
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160 |
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161 | Closed Shell Kohn-Sham (CLKS) Parameters:
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162 | Function Parameters:
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163 | value_accuracy = 6.819199e-10 (1.000000e-08) (computed)
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164 | gradient_accuracy = 6.819199e-08 (1.000000e-06) (computed)
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165 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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166 |
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167 | Molecule:
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168 | Molecular formula: H2O
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169 | molecule<Molecule>: (
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170 | symmetry = c2v
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171 | unit = "angstrom"
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172 | { n atoms geometry }={
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173 | 1 O [ 0.0000000000 0.0000000000 0.3700000000]
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174 | 2 H [ 0.7800000000 0.0000000000 -0.1800000000]
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175 | 3 H [ -0.7800000000 -0.0000000000 -0.1800000000]
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176 | }
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177 | )
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178 | Atomic Masses:
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179 | 15.99491 1.00783 1.00783
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180 |
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181 | GaussianBasisSet:
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182 | nbasis = 30
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183 | nshell = 13
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184 | nprim = 24
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185 | name = "6-311G**"
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186 | SCF Parameters:
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187 | maxiter = 40
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188 | density_reset_frequency = 10
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189 | level_shift = 0.000000
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190 |
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191 | CLSCF Parameters:
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192 | charge = 0.0000000000
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193 | ndocc = 5
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194 | docc = [ 3 0 1 1 ]
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195 |
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196 | Functional:
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197 | Object of type SlaterXFunctional
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198 | Integrator:
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199 | RadialAngularIntegrator:
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200 | Pruned fine grid employed
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201 | CPU Wall
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202 | mpqc: 6.65 7.30
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203 | calc: 6.43 7.08
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204 | compute gradient: 2.26 2.58
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205 | nuc rep: 0.00 0.00
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206 | one electron gradient: 0.03 0.02
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207 | overlap gradient: 0.01 0.01
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208 | two electron gradient: 2.22 2.55
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209 | grad: 2.22 2.55
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210 | integrate: 1.80 2.10
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211 | two-body: 0.18 0.20
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212 | contribution: 0.08 0.10
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213 | start thread: 0.08 0.08
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214 | stop thread: 0.00 0.02
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215 | setup: 0.10 0.10
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216 | vector: 4.17 4.50
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217 | density: 0.00 0.00
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218 | evals: 0.02 0.01
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219 | extrap: 0.01 0.02
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220 | fock: 3.89 4.22
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221 | accum: 0.00 0.00
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222 | init pmax: 0.00 0.00
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223 | integrate: 3.61 3.91
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224 | local data: 0.00 0.00
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225 | setup: 0.03 0.04
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226 | start thread: 0.11 0.11
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227 | stop thread: 0.00 0.02
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228 | sum: 0.00 0.00
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229 | symm: 0.05 0.05
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230 | input: 0.22 0.22
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231 | vector: 0.04 0.04
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232 | density: 0.00 0.00
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233 | evals: 0.02 0.00
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234 | extrap: 0.01 0.01
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235 | fock: 0.00 0.02
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236 | accum: 0.00 0.00
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237 | ao_gmat: 0.00 0.01
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238 | start thread: 0.00 0.00
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239 | stop thread: 0.00 0.00
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240 | init pmax: 0.00 0.00
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241 | local data: 0.00 0.00
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242 | setup: 0.00 0.01
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243 | sum: 0.00 0.00
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244 | symm: 0.00 0.01
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245 |
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246 | End Time: Sat Apr 6 14:04:00 2002
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247 |
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