1 |
|
---|
2 | MPQC: Massively Parallel Quantum Chemistry
|
---|
3 | Version 2.1.0-alpha-gcc3
|
---|
4 |
|
---|
5 | Machine: i686-pc-linux-gnu
|
---|
6 | User: cljanss@aros.ca.sandia.gov
|
---|
7 | Start Time: Sat Apr 6 14:03:28 2002
|
---|
8 |
|
---|
9 | Using ProcMessageGrp for message passing (number of nodes = 1).
|
---|
10 | Using PthreadThreadGrp for threading (number of threads = 2).
|
---|
11 | Using ProcMemoryGrp for distributed shared memory.
|
---|
12 | Total number of processors = 2
|
---|
13 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
|
---|
14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-311gSS.kv.
|
---|
15 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
|
---|
16 |
|
---|
17 | CLSCF::init: total charge = 0
|
---|
18 |
|
---|
19 | Starting from core Hamiltonian guess
|
---|
20 |
|
---|
21 | Using symmetric orthogonalization.
|
---|
22 | n(SO): 4 0 2 1
|
---|
23 | Maximum orthogonalization residual = 1.91709
|
---|
24 | Minimum orthogonalization residual = 0.341238
|
---|
25 | docc = [ 3 0 1 1 ]
|
---|
26 | nbasis = 7
|
---|
27 |
|
---|
28 | CLSCF::init: total charge = 0
|
---|
29 |
|
---|
30 | Projecting guess wavefunction into the present basis set
|
---|
31 |
|
---|
32 | SCF::compute: energy accuracy = 1.0000000e-06
|
---|
33 |
|
---|
34 | integral intermediate storage = 31876 bytes
|
---|
35 | integral cache = 7967676 bytes
|
---|
36 | nuclear repulsion energy = 9.2104861547
|
---|
37 |
|
---|
38 | 565 integrals
|
---|
39 | iter 1 energy = -74.6502873692 delta = 7.46840e-01
|
---|
40 | 565 integrals
|
---|
41 | iter 2 energy = -74.9396377448 delta = 2.26644e-01
|
---|
42 | 565 integrals
|
---|
43 | iter 3 energy = -74.9587707069 delta = 6.77230e-02
|
---|
44 | 565 integrals
|
---|
45 | iter 4 energy = -74.9598296477 delta = 1.97077e-02
|
---|
46 | 565 integrals
|
---|
47 | iter 5 energy = -74.9598805126 delta = 4.60729e-03
|
---|
48 | 565 integrals
|
---|
49 | iter 6 energy = -74.9598807963 delta = 3.15131e-04
|
---|
50 | 565 integrals
|
---|
51 | iter 7 energy = -74.9598807973 delta = 2.01451e-05
|
---|
52 |
|
---|
53 | HOMO is 1 B2 = -0.387218
|
---|
54 | LUMO is 4 A1 = 0.598273
|
---|
55 |
|
---|
56 | total scf energy = -74.9598807973
|
---|
57 |
|
---|
58 | Projecting the guess density.
|
---|
59 |
|
---|
60 | The number of electrons in the guess density = 10
|
---|
61 | Using symmetric orthogonalization.
|
---|
62 | n(SO): 14 2 9 5
|
---|
63 | Maximum orthogonalization residual = 4.47996
|
---|
64 | Minimum orthogonalization residual = 0.0185137
|
---|
65 | The number of electrons in the projected density = 9.99141
|
---|
66 |
|
---|
67 | docc = [ 3 0 1 1 ]
|
---|
68 | nbasis = 30
|
---|
69 |
|
---|
70 | Molecular formula H2O
|
---|
71 |
|
---|
72 | MPQC options:
|
---|
73 | matrixkit = <ReplSCMatrixKit>
|
---|
74 | filename = methods_clks_blyp
|
---|
75 | restart_file = methods_clks_blyp.ckpt
|
---|
76 | restart = yes
|
---|
77 | checkpoint = no
|
---|
78 | savestate = no
|
---|
79 | do_energy = yes
|
---|
80 | do_gradient = yes
|
---|
81 | optimize = no
|
---|
82 | write_pdb = no
|
---|
83 | print_mole = yes
|
---|
84 | print_timings = yes
|
---|
85 |
|
---|
86 | SCF::compute: energy accuracy = 1.0000000e-08
|
---|
87 |
|
---|
88 | Initializing ShellExtent
|
---|
89 | nshell = 13
|
---|
90 | ncell = 54760
|
---|
91 | ave nsh/cell = 1.57949
|
---|
92 | max nsh/cell = 13
|
---|
93 | integral intermediate storage = 260598 bytes
|
---|
94 | integral cache = 15731962 bytes
|
---|
95 | nuclear repulsion energy = 9.2104861547
|
---|
96 |
|
---|
97 | Total integration points = 4049
|
---|
98 | Integrated electron density error = -0.000245176044
|
---|
99 | iter 1 energy = -76.0581370190 delta = 9.87174e-02
|
---|
100 | Total integration points = 11317
|
---|
101 | Integrated electron density error = -0.000005675087
|
---|
102 | iter 2 energy = -76.4114475147 delta = 4.91685e-02
|
---|
103 | Total integration points = 11317
|
---|
104 | Integrated electron density error = -0.000012542080
|
---|
105 | iter 3 energy = -76.3972308133 delta = 1.49140e-02
|
---|
106 | Total integration points = 11317
|
---|
107 | Integrated electron density error = -0.000008497783
|
---|
108 | iter 4 energy = -76.4268108642 delta = 8.56296e-03
|
---|
109 | Total integration points = 46071
|
---|
110 | Integrated electron density error = 0.000000626868
|
---|
111 | iter 5 energy = -76.4270809264 delta = 7.51974e-04
|
---|
112 | Total integration points = 46071
|
---|
113 | Integrated electron density error = 0.000000626561
|
---|
114 | iter 6 energy = -76.4270913941 delta = 1.48590e-04
|
---|
115 | Total integration points = 46071
|
---|
116 | Integrated electron density error = 0.000000626367
|
---|
117 | iter 7 energy = -76.4270914047 delta = 6.37911e-06
|
---|
118 | Total integration points = 46071
|
---|
119 | Integrated electron density error = 0.000000626373
|
---|
120 | iter 8 energy = -76.4270914055 delta = 1.52534e-06
|
---|
121 | Total integration points = 46071
|
---|
122 | Integrated electron density error = 0.000000626377
|
---|
123 | iter 9 energy = -76.4270914055 delta = 1.12807e-07
|
---|
124 |
|
---|
125 | HOMO is 1 B2 = -0.232690
|
---|
126 | LUMO is 4 A1 = 0.009257
|
---|
127 |
|
---|
128 | total scf energy = -76.4270914055
|
---|
129 |
|
---|
130 | SCF::compute: gradient accuracy = 1.0000000e-06
|
---|
131 |
|
---|
132 | Initializing ShellExtent
|
---|
133 | nshell = 13
|
---|
134 | ncell = 54760
|
---|
135 | ave nsh/cell = 1.57949
|
---|
136 | max nsh/cell = 13
|
---|
137 | Total integration points = 46071
|
---|
138 | Integrated electron density error = 0.000000626627
|
---|
139 | Total Gradient:
|
---|
140 | 1 O -0.0000000000 0.0000000000 -0.0301947561
|
---|
141 | 2 H -0.0066638770 0.0000000000 0.0150973780
|
---|
142 | 3 H 0.0066638771 -0.0000000000 0.0150973781
|
---|
143 |
|
---|
144 | Value of the MolecularEnergy: -76.4270914055
|
---|
145 |
|
---|
146 |
|
---|
147 | Gradient of the MolecularEnergy:
|
---|
148 | 1 -0.0000000000
|
---|
149 | 2 0.0000000000
|
---|
150 | 3 -0.0301947561
|
---|
151 | 4 -0.0066638770
|
---|
152 | 5 0.0000000000
|
---|
153 | 6 0.0150973780
|
---|
154 | 7 0.0066638771
|
---|
155 | 8 -0.0000000000
|
---|
156 | 9 0.0150973781
|
---|
157 |
|
---|
158 | Closed Shell Kohn-Sham (CLKS) Parameters:
|
---|
159 | Function Parameters:
|
---|
160 | value_accuracy = 3.157765e-09 (1.000000e-08) (computed)
|
---|
161 | gradient_accuracy = 3.157765e-07 (1.000000e-06) (computed)
|
---|
162 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
163 |
|
---|
164 | Molecule:
|
---|
165 | Molecular formula: H2O
|
---|
166 | molecule<Molecule>: (
|
---|
167 | symmetry = c2v
|
---|
168 | unit = "angstrom"
|
---|
169 | { n atoms geometry }={
|
---|
170 | 1 O [ 0.0000000000 0.0000000000 0.3700000000]
|
---|
171 | 2 H [ 0.7800000000 0.0000000000 -0.1800000000]
|
---|
172 | 3 H [ -0.7800000000 -0.0000000000 -0.1800000000]
|
---|
173 | }
|
---|
174 | )
|
---|
175 | Atomic Masses:
|
---|
176 | 15.99491 1.00783 1.00783
|
---|
177 |
|
---|
178 | GaussianBasisSet:
|
---|
179 | nbasis = 30
|
---|
180 | nshell = 13
|
---|
181 | nprim = 24
|
---|
182 | name = "6-311G**"
|
---|
183 | SCF Parameters:
|
---|
184 | maxiter = 40
|
---|
185 | density_reset_frequency = 10
|
---|
186 | level_shift = 0.000000
|
---|
187 |
|
---|
188 | CLSCF Parameters:
|
---|
189 | charge = 0.0000000000
|
---|
190 | ndocc = 5
|
---|
191 | docc = [ 3 0 1 1 ]
|
---|
192 |
|
---|
193 | Functional:
|
---|
194 | Sum of Functionals:
|
---|
195 | +1.0000000000000000
|
---|
196 | Object of type SlaterXFunctional
|
---|
197 | +1.0000000000000000
|
---|
198 | Object of type Becke88XFunctional
|
---|
199 | +1.0000000000000000
|
---|
200 | Object of type LYPCFunctional
|
---|
201 | Integrator:
|
---|
202 | RadialAngularIntegrator:
|
---|
203 | Pruned fine grid employed
|
---|
204 | CPU Wall
|
---|
205 | mpqc: 19.34 24.71
|
---|
206 | calc: 19.12 24.49
|
---|
207 | compute gradient: 10.85 13.12
|
---|
208 | nuc rep: 0.00 0.00
|
---|
209 | one electron gradient: 0.03 0.02
|
---|
210 | overlap gradient: 0.01 0.01
|
---|
211 | two electron gradient: 10.81 13.08
|
---|
212 | grad: 10.81 13.08
|
---|
213 | integrate: 10.39 12.64
|
---|
214 | two-body: 0.18 0.20
|
---|
215 | contribution: 0.08 0.10
|
---|
216 | start thread: 0.08 0.08
|
---|
217 | stop thread: 0.00 0.02
|
---|
218 | setup: 0.10 0.10
|
---|
219 | vector: 8.27 11.38
|
---|
220 | density: 0.00 0.00
|
---|
221 | evals: 0.00 0.01
|
---|
222 | extrap: 0.01 0.02
|
---|
223 | fock: 8.00 11.09
|
---|
224 | accum: 0.00 0.00
|
---|
225 | init pmax: 0.00 0.00
|
---|
226 | integrate: 7.73 10.81
|
---|
227 | local data: 0.01 0.00
|
---|
228 | setup: 0.03 0.03
|
---|
229 | start thread: 0.10 0.11
|
---|
230 | stop thread: 0.00 0.01
|
---|
231 | sum: 0.00 0.00
|
---|
232 | symm: 0.04 0.04
|
---|
233 | input: 0.22 0.22
|
---|
234 | vector: 0.05 0.04
|
---|
235 | density: 0.00 0.00
|
---|
236 | evals: 0.01 0.00
|
---|
237 | extrap: 0.01 0.01
|
---|
238 | fock: 0.02 0.02
|
---|
239 | accum: 0.00 0.00
|
---|
240 | ao_gmat: 0.00 0.01
|
---|
241 | start thread: 0.00 0.00
|
---|
242 | stop thread: 0.00 0.00
|
---|
243 | init pmax: 0.00 0.00
|
---|
244 | local data: 0.00 0.00
|
---|
245 | setup: 0.01 0.01
|
---|
246 | sum: 0.00 0.00
|
---|
247 | symm: 0.00 0.01
|
---|
248 |
|
---|
249 | End Time: Sat Apr 6 14:03:53 2002
|
---|
250 |
|
---|