1 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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2 |
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3 | MPQC: Massively Parallel Quantum Chemistry
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4 | Version 2.1.0-alpha-gcc3
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5 |
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6 | Machine: i686-pc-linux-gnu
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7 | User: cljanss@aros.ca.sandia.gov
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8 | Start Time: Sat Apr 6 14:01:02 2002
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9 |
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10 | Using ProcMessageGrp for message passing (number of nodes = 1).
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11 | Using PthreadThreadGrp for threading (number of threads = 2).
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12 | Using ProcMemoryGrp for distributed shared memory.
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13 | Total number of processors = 2
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14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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15 | Molecule: setting point group to c2v
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16 |
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17 | IntCoorGen: generated 3 coordinates.
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18 | Forming optimization coordinates:
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19 | SymmMolecularCoor::form_variable_coordinates()
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20 | expected 3 coordinates
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21 | found 2 variable coordinates
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22 | found 0 constant coordinates
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23 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-31gS.kv.
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24 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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25 |
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26 | HSOSSCF::init: total charge = 0
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27 |
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28 | Starting from core Hamiltonian guess
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29 |
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30 | Using symmetric orthogonalization.
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31 | n(SO): 4 0 1 2
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32 | Maximum orthogonalization residual = 1.94235
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33 | Minimum orthogonalization residual = 0.275215
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34 | docc = [ 2 0 0 1 ]
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35 | socc = [ 1 0 1 0 ]
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36 |
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37 | HSOSSCF::init: total charge = 0
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38 |
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39 | Projecting guess wavefunction into the present basis set
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40 |
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41 | SCF::compute: energy accuracy = 1.0000000e-06
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42 |
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43 | nuclear repulsion energy = 6.0605491858
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44 |
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45 | iter 1 energy = -38.1820699187 delta = 5.64824e-01
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46 | iter 2 energy = -38.4083575544 delta = 1.45984e-01
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47 | iter 3 energy = -38.4168336215 delta = 3.56591e-02
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48 | iter 4 energy = -38.4175716540 delta = 1.01929e-02
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49 | iter 5 energy = -38.4176486511 delta = 4.37691e-03
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50 | iter 6 energy = -38.4176552372 delta = 6.66000e-04
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51 | iter 7 energy = -38.4176560606 delta = 2.30956e-04
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52 | iter 8 energy = -38.4176560751 delta = 4.38489e-05
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53 | iter 9 energy = -38.4176560764 delta = 1.13693e-05
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54 | iter 10 energy = -38.4176560765 delta = 3.21030e-06
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55 |
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56 | HOMO is 1 B1 = 0.003112
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57 | LUMO is 2 B2 = 0.704260
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58 |
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59 | total scf energy = -38.4176560765
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60 |
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61 | Projecting the guess density.
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62 |
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63 | The number of electrons in the guess density = 8
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64 | Using symmetric orthogonalization.
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65 | n(SO): 10 1 3 5
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66 | Maximum orthogonalization residual = 4.63968
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67 | Minimum orthogonalization residual = 0.0296946
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68 | The number of electrons in the projected density = 7.9909
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69 |
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70 | docc = [ 2 0 0 1 ]
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71 | socc = [ 1 0 1 0 ]
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72 |
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73 | Molecular formula CH2
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74 |
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75 | MPQC options:
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76 | matrixkit = <ReplSCMatrixKit>
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77 | filename = input_rhfch2opt
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78 | restart_file = input_rhfch2opt.ckpt
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79 | restart = no
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80 | checkpoint = no
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81 | savestate = no
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82 | do_energy = yes
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83 | do_gradient = no
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84 | optimize = yes
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85 | write_pdb = no
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86 | print_mole = yes
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87 | print_timings = yes
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88 |
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89 | SCF::compute: energy accuracy = 1.0000000e-06
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90 |
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91 | nuclear repulsion energy = 6.0605491858
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92 |
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93 | iter 1 energy = -38.8355220823 delta = 1.79777e-01
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94 | iter 2 energy = -38.8951868245 delta = 2.71836e-02
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95 | iter 3 energy = -38.8993815408 delta = 5.61708e-03
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96 | iter 4 energy = -38.9001033746 delta = 2.78189e-03
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97 | iter 5 energy = -38.9002102224 delta = 1.29839e-03
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98 | iter 6 energy = -38.9002153055 delta = 3.34688e-04
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99 | iter 7 energy = -38.9002155880 delta = 9.47632e-05
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100 | iter 8 energy = -38.9002156092 delta = 2.69195e-05
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101 | iter 9 energy = -38.9002156113 delta = 7.44356e-06
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102 | iter 10 energy = -38.9002156117 delta = 2.94032e-06
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103 | iter 11 energy = -38.9002156117 delta = 1.00427e-06
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104 |
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105 | HOMO is 1 B1 = -0.100853
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106 | LUMO is 4 A1 = 0.279000
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107 |
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108 | total scf energy = -38.9002156117
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109 |
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110 | SCF::compute: gradient accuracy = 1.0000000e-04
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111 |
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112 | Total Gradient:
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113 | 1 C 0.0000000000 -0.0000000000 -0.0720580006
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114 | 2 H -0.0000000000 -0.0095603194 0.0360290003
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115 | 3 H -0.0000000000 0.0095603194 0.0360290003
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116 |
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117 | Max Gradient : 0.0720580006 0.0001000000 no
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118 | Max Displacement : 0.1620066092 0.0001000000 no
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119 | Gradient*Displace: 0.0196876449 0.0001000000 no
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120 |
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121 | taking step of size 0.265114
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122 |
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123 | HSOSHF: changing atomic coordinates:
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124 | Molecular formula: CH2
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125 | molecule<Molecule>: (
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126 | symmetry = c2v
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127 | unit = "angstrom"
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128 | { n atoms geometry }={
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129 | 1 C [ 0.0000000000 0.0000000000 -0.0143644998]
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130 | 2 H [ -0.0000000000 0.9172454917 0.5530401825]
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131 | 3 H [ -0.0000000000 -0.9172454917 0.5530401825]
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132 | }
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133 | )
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134 | Atomic Masses:
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135 | 12.00000 1.00783 1.00783
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136 |
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137 | SCF::compute: energy accuracy = 5.3968843e-07
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138 |
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139 | nuclear repulsion energy = 6.1760682320
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140 |
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141 | Using symmetric orthogonalization.
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142 | n(SO): 10 1 3 5
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143 | Maximum orthogonalization residual = 4.64492
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144 | Minimum orthogonalization residual = 0.031516
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145 | iter 1 energy = -38.9080202933 delta = 1.76886e-01
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146 | iter 2 energy = -38.9133276944 delta = 9.01131e-03
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147 | iter 3 energy = -38.9136366775 delta = 1.52789e-03
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148 | iter 4 energy = -38.9136756963 delta = 5.29801e-04
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149 | iter 5 energy = -38.9136798935 delta = 2.37305e-04
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150 | iter 6 energy = -38.9136801403 delta = 8.09872e-05
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151 | iter 7 energy = -38.9136801710 delta = 2.12493e-05
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152 | iter 8 energy = -38.9136801738 delta = 9.81396e-06
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153 | iter 9 energy = -38.9136801741 delta = 2.53524e-06
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154 | iter 10 energy = -38.9136801741 delta = 8.17308e-07
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155 |
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156 | HOMO is 1 B1 = -0.098929
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157 | LUMO is 4 A1 = 0.280903
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158 |
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159 | total scf energy = -38.9136801741
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160 |
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161 | SCF::compute: gradient accuracy = 5.3968843e-05
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162 |
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163 | Total Gradient:
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164 | 1 C 0.0000000000 0.0000000000 -0.0263312302
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165 | 2 H -0.0000000000 -0.0054731622 0.0131656151
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166 | 3 H -0.0000000000 0.0054731622 0.0131656151
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167 |
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168 | Max Gradient : 0.0263312302 0.0001000000 no
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169 | Max Displacement : 0.1053906270 0.0001000000 no
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170 | Gradient*Displace: 0.0049798854 0.0001000000 no
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171 |
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172 | taking step of size 0.172570
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173 |
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174 | HSOSHF: changing atomic coordinates:
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175 | Molecular formula: CH2
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176 | molecule<Molecule>: (
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177 | symmetry = c2v
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178 | unit = "angstrom"
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179 | { n atoms geometry }={
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180 | 1 C [ 0.0000000000 0.0000000000 0.0414058223]
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181 | 2 H [ -0.0000000000 0.9567555809 0.5251550215]
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182 | 3 H [ -0.0000000000 -0.9567555809 0.5251550215]
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183 | }
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184 | )
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185 | Atomic Masses:
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186 | 12.00000 1.00783 1.00783
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187 |
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188 | SCF::compute: energy accuracy = 2.3313881e-07
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189 |
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190 | nuclear repulsion energy = 6.1996311673
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191 |
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192 | Using symmetric orthogonalization.
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193 | n(SO): 10 1 3 5
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194 | Maximum orthogonalization residual = 4.63302
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195 | Minimum orthogonalization residual = 0.0339208
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196 | iter 1 energy = -38.9139183213 delta = 1.76222e-01
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197 | iter 2 energy = -38.9163445085 delta = 4.84289e-03
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198 | iter 3 energy = -38.9164798748 delta = 1.18116e-03
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199 | iter 4 energy = -38.9164955692 delta = 3.83493e-04
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200 | iter 5 energy = -38.9164968313 delta = 1.48385e-04
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201 | iter 6 energy = -38.9164969497 delta = 7.05173e-05
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202 | iter 7 energy = -38.9164969694 delta = 1.57359e-05
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203 | iter 8 energy = -38.9164969706 delta = 7.35453e-06
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204 | iter 9 energy = -38.9164969708 delta = 2.20066e-06
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205 | iter 10 energy = -38.9164969708 delta = 4.58123e-07
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206 | iter 11 energy = -38.9164969708 delta = 2.80049e-07
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207 |
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208 | HOMO is 1 B1 = -0.097938
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209 | LUMO is 4 A1 = 0.276716
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210 |
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211 | total scf energy = -38.9164969708
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212 |
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213 | SCF::compute: gradient accuracy = 2.3313881e-05
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214 |
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215 | Total Gradient:
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216 | 1 C 0.0000000000 0.0000000000 -0.0039579013
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217 | 2 H -0.0000000000 -0.0009883195 0.0019789506
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218 | 3 H -0.0000000000 0.0009883195 0.0019789506
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219 |
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220 | Max Gradient : 0.0039579013 0.0001000000 no
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221 | Max Displacement : 0.0194159967 0.0001000000 no
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222 | Gradient*Displace: 0.0001416226 0.0001000000 no
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223 |
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224 | taking step of size 0.031644
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225 |
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226 | HSOSHF: changing atomic coordinates:
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227 | Molecular formula: CH2
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228 | molecule<Molecule>: (
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229 | symmetry = c2v
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230 | unit = "angstrom"
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231 | { n atoms geometry }={
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232 | 1 C [ 0.0000000000 0.0000000000 0.0516803260]
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233 | 2 H [ -0.0000000000 0.9638106007 0.5200177696]
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234 | 3 H [ -0.0000000000 -0.9638106007 0.5200177696]
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235 | }
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236 | )
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237 | Atomic Masses:
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238 | 12.00000 1.00783 1.00783
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239 |
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240 | SCF::compute: energy accuracy = 3.8831096e-08
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241 |
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242 | nuclear repulsion energy = 6.2005043053
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243 |
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244 | Using symmetric orthogonalization.
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245 | n(SO): 10 1 3 5
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246 | Maximum orthogonalization residual = 4.63
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247 | Minimum orthogonalization residual = 0.0344012
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248 | iter 1 energy = -38.9164811442 delta = 1.75686e-01
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249 | iter 2 energy = -38.9165690339 delta = 8.63726e-04
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250 | iter 3 energy = -38.9165741136 delta = 2.43258e-04
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251 | iter 4 energy = -38.9165747133 delta = 8.21640e-05
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252 | iter 5 energy = -38.9165747531 delta = 2.95731e-05
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253 | iter 6 energy = -38.9165747597 delta = 1.73598e-05
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254 | iter 7 energy = -38.9165747606 delta = 2.39406e-06
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255 | iter 8 energy = -38.9165747606 delta = 8.23911e-07
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256 | iter 9 energy = -38.9165747607 delta = 3.27858e-07
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257 | iter 10 energy = -38.9165747607 delta = 9.92597e-08
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258 |
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259 | HOMO is 1 B1 = -0.097766
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260 | LUMO is 4 A1 = 0.275487
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261 |
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262 | total scf energy = -38.9165747607
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263 |
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264 | SCF::compute: gradient accuracy = 3.8831096e-06
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265 |
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266 | Total Gradient:
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267 | 1 C 0.0000000000 -0.0000000000 -0.0004642508
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268 | 2 H -0.0000000000 -0.0000439828 0.0002321254
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269 | 3 H -0.0000000000 0.0000439828 0.0002321254
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270 |
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271 | Max Gradient : 0.0004642508 0.0001000000 no
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272 | Max Displacement : 0.0023233826 0.0001000000 no
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273 | Gradient*Displace: 0.0000017348 0.0001000000 yes
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274 |
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275 | taking step of size 0.003699
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276 |
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277 | HSOSHF: changing atomic coordinates:
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278 | Molecular formula: CH2
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279 | molecule<Molecule>: (
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280 | symmetry = c2v
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281 | unit = "angstrom"
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282 | { n atoms geometry }={
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283 | 1 C [ 0.0000000000 0.0000000000 0.0529098072]
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284 | 2 H [ -0.0000000000 0.9645133738 0.5194030290]
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285 | 3 H [ -0.0000000000 -0.9645133738 0.5194030290]
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286 | }
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287 | )
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288 | Atomic Masses:
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289 | 12.00000 1.00783 1.00783
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290 |
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291 | SCF::compute: energy accuracy = 3.5742105e-09
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292 |
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293 | nuclear repulsion energy = 6.2012563150
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294 |
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295 | Using symmetric orthogonalization.
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296 | n(SO): 10 1 3 5
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297 | Maximum orthogonalization residual = 4.62989
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298 | Minimum orthogonalization residual = 0.034447
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299 | iter 1 energy = -38.9165727929 delta = 1.75590e-01
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300 | iter 2 energy = -38.9165755574 delta = 1.11576e-04
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301 | iter 3 energy = -38.9165756317 delta = 2.94174e-05
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302 | iter 4 energy = -38.9165756413 delta = 1.00014e-05
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303 | iter 5 energy = -38.9165756421 delta = 3.89049e-06
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304 | iter 6 energy = -38.9165756422 delta = 2.11879e-06
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305 | iter 7 energy = -38.9165756422 delta = 3.62798e-07
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306 | iter 8 energy = -38.9165756422 delta = 1.57420e-07
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307 | iter 9 energy = -38.9165756422 delta = 5.03765e-08
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308 | iter 10 energy = -38.9165756422 delta = 1.56545e-08
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309 | iter 11 energy = -38.9165756422 delta = 4.11360e-09
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310 |
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311 | HOMO is 1 B1 = -0.097745
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312 | LUMO is 4 A1 = 0.275372
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313 |
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314 | total scf energy = -38.9165756422
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315 |
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316 | SCF::compute: gradient accuracy = 3.5742105e-07
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317 |
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318 | Total Gradient:
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319 | 1 C 0.0000000000 0.0000000000 0.0000060431
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320 | 2 H -0.0000000000 -0.0000191829 -0.0000030216
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321 | 3 H -0.0000000000 0.0000191829 -0.0000030216
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322 |
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323 | Max Gradient : 0.0000191829 0.0001000000 yes
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324 | Max Displacement : 0.0000875632 0.0001000000 yes
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325 | Gradient*Displace: 0.0000000030 0.0001000000 yes
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326 |
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327 | All convergence criteria have been met.
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328 | The optimization has converged.
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329 |
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330 | Value of the MolecularEnergy: -38.9165756422
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331 |
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332 | Function Parameters:
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333 | value_accuracy = 1.703794e-09 (3.574211e-09) (computed)
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334 | gradient_accuracy = 1.703794e-07 (3.574211e-07) (computed)
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335 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
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336 |
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337 | Molecular Coordinates:
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338 | IntMolecularCoor Parameters:
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339 | update_bmat = no
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340 | scale_bonds = 1
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341 | scale_bends = 1
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342 | scale_tors = 1
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343 | scale_outs = 1
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344 | symmetry_tolerance = 1.000000e-05
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345 | simple_tolerance = 1.000000e-03
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346 | coordinate_tolerance = 1.000000e-07
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347 | have_fixed_values = 0
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348 | max_update_steps = 100
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349 | max_update_disp = 0.500000
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350 | have_fixed_values = 0
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351 |
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352 | Molecular formula: CH2
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353 | molecule<Molecule>: (
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354 | symmetry = c2v
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355 | unit = "angstrom"
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356 | { n atoms geometry }={
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357 | 1 C [ 0.0000000000 0.0000000000 0.0529098072]
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358 | 2 H [ -0.0000000000 0.9645133738 0.5194030290]
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359 | 3 H [ -0.0000000000 -0.9645133738 0.5194030290]
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360 | }
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361 | )
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362 | Atomic Masses:
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363 | 12.00000 1.00783 1.00783
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364 |
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365 | Bonds:
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366 | STRE s1 1.07140 1 2 C-H
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367 | STRE s2 1.07140 1 3 C-H
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368 | Bends:
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369 | BEND b1 128.37793 2 1 3 H-C-H
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370 |
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371 | SymmMolecularCoor Parameters:
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372 | change_coordinates = no
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373 | transform_hessian = yes
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374 | max_kappa2 = 10.000000
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375 |
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376 | GaussianBasisSet:
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377 | nbasis = 19
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378 | nshell = 8
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379 | nprim = 19
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380 | name = "6-31G*"
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381 | Natural Population Analysis:
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382 | n atom charge ne(S) ne(P) ne(D)
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383 | 1 C -0.219149 3.267183 2.946690 0.005275
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384 | 2 H 0.109574 0.890426
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385 | 3 H 0.109574 0.890426
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386 |
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387 | SCF Parameters:
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388 | maxiter = 100
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389 | density_reset_frequency = 10
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390 | level_shift = 0.250000
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391 |
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392 | HSOSSCF Parameters:
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393 | charge = 0
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394 | ndocc = 3
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395 | nsocc = 2
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396 | docc = [ 2 0 0 1 ]
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397 | socc = [ 1 0 1 0 ]
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398 |
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399 | CPU Wall
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400 | mpqc: 1.93 1.92
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401 | NAO: 0.02 0.02
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402 | calc: 1.68 1.67
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403 | compute gradient: 0.53 0.57
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404 | nuc rep: 0.00 0.00
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405 | one electron gradient: 0.06 0.08
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406 | overlap gradient: 0.04 0.03
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407 | two electron gradient: 0.43 0.46
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408 | vector: 1.11 1.07
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409 | density: 0.06 0.03
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410 | evals: 0.04 0.06
|
---|
411 | extrap: 0.08 0.10
|
---|
412 | fock: 0.77 0.75
|
---|
413 | start thread: 0.15 0.15
|
---|
414 | stop thread: 0.00 0.01
|
---|
415 | input: 0.23 0.23
|
---|
416 | vector: 0.09 0.09
|
---|
417 | density: 0.00 0.00
|
---|
418 | evals: 0.02 0.01
|
---|
419 | extrap: 0.00 0.01
|
---|
420 | fock: 0.06 0.06
|
---|
421 | start thread: 0.00 0.00
|
---|
422 | stop thread: 0.00 0.00
|
---|
423 |
|
---|
424 | End Time: Sat Apr 6 14:01:03 2002
|
---|
425 |
|
---|