1 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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2 |
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3 | MPQC: Massively Parallel Quantum Chemistry
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4 | Version 2.1.0-alpha-gcc3
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5 |
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6 | Machine: i686-pc-linux-gnu
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7 | User: cljanss@aros.ca.sandia.gov
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8 | Start Time: Sat Apr 6 14:00:52 2002
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9 |
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10 | Using ProcMessageGrp for message passing (number of nodes = 1).
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11 | Using PthreadThreadGrp for threading (number of threads = 2).
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12 | Using ProcMemoryGrp for distributed shared memory.
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13 | Total number of processors = 2
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14 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/atominfo.kv.
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15 | Molecule: setting point group to c2v
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16 |
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17 | IntCoorGen: generated 3 coordinates.
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18 | Forming optimization coordinates:
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19 | SymmMolecularCoor::form_variable_coordinates()
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20 | expected 3 coordinates
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21 | found 2 variable coordinates
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22 | found 0 constant coordinates
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23 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/6-31gS.kv.
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24 | Reading file /usr/local/mpqc/2.1.0-alpha-gcc3/share/basis/sto-3g.kv.
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25 |
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26 | CLSCF::init: total charge = 0
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27 |
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28 | Starting from core Hamiltonian guess
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29 |
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30 | Using symmetric orthogonalization.
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31 | n(SO): 4 0 1 2
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32 | Maximum orthogonalization residual = 1.94039
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33 | Minimum orthogonalization residual = 0.335627
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34 | docc = [ 3 0 1 1 ]
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35 | nbasis = 7
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36 |
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37 | CLSCF::init: total charge = 0
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38 |
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39 | Projecting guess wavefunction into the present basis set
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40 |
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41 | SCF::compute: energy accuracy = 1.0000000e-06
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42 |
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43 | integral intermediate storage = 31876 bytes
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44 | integral cache = 7967676 bytes
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45 | nuclear repulsion energy = 9.2914265473
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46 |
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47 | 565 integrals
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48 | iter 1 energy = -74.6442059283 delta = 7.46913e-01
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49 | 565 integrals
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50 | iter 2 energy = -74.9411785471 delta = 2.32701e-01
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51 | 565 integrals
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52 | iter 3 energy = -74.9598835707 delta = 6.74768e-02
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53 | 565 integrals
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54 | iter 4 energy = -74.9608017389 delta = 1.82839e-02
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55 | 565 integrals
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56 | iter 5 energy = -74.9608457808 delta = 4.27179e-03
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57 | 565 integrals
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58 | iter 6 energy = -74.9608460189 delta = 2.87494e-04
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59 | 565 integrals
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60 | iter 7 energy = -74.9608460194 delta = 1.50392e-05
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61 |
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62 | HOMO is 1 B1 = -0.391179
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63 | LUMO is 4 A1 = 0.614055
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64 |
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65 | total scf energy = -74.9608460194
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66 |
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67 | Projecting the guess density.
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68 |
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69 | The number of electrons in the guess density = 10
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70 | Using symmetric orthogonalization.
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71 | n(SO): 10 1 3 5
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72 | Maximum orthogonalization residual = 4.69613
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73 | Minimum orthogonalization residual = 0.0219193
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74 | The number of electrons in the projected density = 9.95801
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75 |
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76 | docc = [ 3 0 1 1 ]
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77 | nbasis = 19
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78 |
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79 | Molecular formula H2O
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80 |
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81 | MPQC options:
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82 | matrixkit = <ReplSCMatrixKit>
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83 | filename = input_ksh2oco
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84 | restart_file = input_ksh2oco.ckpt
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85 | restart = no
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86 | checkpoint = no
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87 | savestate = no
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88 | do_energy = yes
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89 | do_gradient = no
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90 | optimize = yes
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91 | write_pdb = no
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92 | print_mole = yes
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93 | print_timings = yes
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94 |
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95 | SCF::compute: energy accuracy = 1.0000000e-06
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96 |
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97 | Initializing ShellExtent
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98 | nshell = 8
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99 | ncell = 29700
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100 | ave nsh/cell = 1.56054
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101 | max nsh/cell = 8
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102 | integral intermediate storage = 236328 bytes
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103 | integral cache = 7760632 bytes
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104 | nuclear repulsion energy = 9.2914265473
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105 |
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106 | Total integration points = 4049
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107 | Integrated electron density error = -0.000336357342
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108 | iter 1 energy = -75.3981819726 delta = 2.12979e-01
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109 | Total integration points = 11317
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110 | Integrated electron density error = -0.000016642076
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111 | iter 2 energy = -75.5157241384 delta = 9.24487e-02
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112 | Total integration points = 11317
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113 | Integrated electron density error = -0.000024082431
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114 | iter 3 energy = -75.5091968634 delta = 5.49769e-02
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115 | Total integration points = 11317
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116 | Integrated electron density error = -0.000021249196
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117 | iter 4 energy = -75.5840055306 delta = 2.69989e-02
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118 | Total integration points = 11317
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119 | Integrated electron density error = -0.000021163120
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120 | iter 5 energy = -75.5840913366 delta = 9.68543e-04
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121 | Total integration points = 11317
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122 | Integrated electron density error = -0.000021193778
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123 | iter 6 energy = -75.5840970337 delta = 2.35175e-04
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124 | Total integration points = 11317
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125 | Integrated electron density error = -0.000021191218
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126 | iter 7 energy = -75.5840970936 delta = 3.42683e-05
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127 | Total integration points = 11317
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128 | Integrated electron density error = -0.000021191567
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129 | iter 8 energy = -75.5840970966 delta = 6.08866e-06
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130 |
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131 | HOMO is 1 B1 = -0.196971
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132 | LUMO is 4 A1 = 0.073993
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133 |
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134 | total scf energy = -75.5840970966
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135 |
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136 | SCF::compute: gradient accuracy = 1.0000000e-04
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137 |
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138 | Initializing ShellExtent
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139 | nshell = 8
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140 | ncell = 29700
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141 | ave nsh/cell = 1.56054
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142 | max nsh/cell = 8
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143 | Total integration points = 11317
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144 | Integrated electron density error = -0.000021154051
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145 | Total Gradient:
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146 | 1 O 0.0380020756 0.0000000001 -0.0000000007
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147 | 2 H -0.0190010378 -0.0000000001 -0.0230747951
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148 | 3 H -0.0190010378 0.0000000001 0.0230747959
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149 |
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150 | Max Gradient : 0.0380020756 0.0001000000 no
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151 | Max Displacement : 0.0586509809 0.0001000000 no
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152 | Gradient*Displace: 0.0047399147 0.0001000000 no
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153 |
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154 | taking step of size 0.112098
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155 |
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156 | CLKS: changing atomic coordinates:
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157 | Molecular formula: H2O
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158 | molecule<Molecule>: (
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159 | symmetry = c2v
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160 | symmetry_frame = [
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161 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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162 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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163 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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164 | unit = "angstrom"
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165 | { n atoms geometry }={
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166 | 1 O [ -0.0830019992 0.0000000000 0.0000000000]
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167 | 2 H [ 0.5183101657 -0.0000000000 0.7850367647]
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168 | 3 H [ 0.5183101657 -0.0000000000 -0.7850367647]
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169 | }
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170 | )
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171 | Atomic Masses:
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172 | 15.99491 1.00783 1.00783
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173 |
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174 | SCF::compute: energy accuracy = 3.4080618e-07
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175 |
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176 | Initializing ShellExtent
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177 | nshell = 8
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178 | ncell = 29700
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179 | ave nsh/cell = 1.56047
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180 | max nsh/cell = 8
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181 | integral intermediate storage = 236328 bytes
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182 | integral cache = 7760632 bytes
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183 | nuclear repulsion energy = 8.8991934753
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184 |
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185 | Using symmetric orthogonalization.
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186 | n(SO): 10 1 3 5
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187 | Maximum orthogonalization residual = 4.60115
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188 | Minimum orthogonalization residual = 0.0234737
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189 | Total integration points = 4049
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190 | Integrated electron density error = 0.000029624752
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191 | iter 1 energy = -75.5822036016 delta = 2.11810e-01
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192 | Total integration points = 11317
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193 | Integrated electron density error = -0.000001323836
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194 | iter 2 energy = -75.5843307873 delta = 1.44770e-02
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195 | Total integration points = 11317
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196 | Integrated electron density error = -0.000002030426
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197 | iter 3 energy = -75.5832328529 delta = 8.52697e-03
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198 | Total integration points = 11317
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199 | Integrated electron density error = -0.000001618151
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200 | iter 4 energy = -75.5855020871 delta = 4.78374e-03
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201 | Total integration points = 11317
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202 | Integrated electron density error = -0.000001623013
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203 | iter 5 energy = -75.5855031304 delta = 9.05206e-05
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204 | Total integration points = 11317
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205 | Integrated electron density error = -0.000001618744
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206 | iter 6 energy = -75.5855032159 delta = 3.47271e-05
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207 | Total integration points = 11317
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208 | Integrated electron density error = -0.000001618765
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209 | iter 7 energy = -75.5855032159 delta = 4.84809e-07
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210 |
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211 | HOMO is 1 B1 = -0.193566
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212 | LUMO is 4 A1 = 0.061210
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213 |
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214 | total scf energy = -75.5855032159
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215 |
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216 | SCF::compute: gradient accuracy = 3.4080618e-05
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217 |
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218 | Initializing ShellExtent
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219 | nshell = 8
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220 | ncell = 29700
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221 | ave nsh/cell = 1.56047
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222 | max nsh/cell = 8
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223 | Total integration points = 11317
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224 | Integrated electron density error = -0.000001616200
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225 | Total Gradient:
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226 | 1 O -0.0078877611 -0.0000000000 -0.0000000000
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227 | 2 H 0.0039438805 0.0000000000 0.0102503208
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228 | 3 H 0.0039438806 -0.0000000000 -0.0102503207
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229 |
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230 | Max Gradient : 0.0102503208 0.0001000000 no
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231 | Max Displacement : 0.0243330497 0.0001000000 no
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232 | Gradient*Displace: 0.0004999781 0.0001000000 no
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233 |
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234 | taking step of size 0.031634
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235 |
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236 | CLKS: changing atomic coordinates:
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237 | Molecular formula: H2O
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238 | molecule<Molecule>: (
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239 | symmetry = c2v
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240 | symmetry_frame = [
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241 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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242 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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243 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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244 | unit = "angstrom"
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245 | { n atoms geometry }={
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246 | 1 O [ -0.0829512364 0.0000000000 0.0000000000]
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247 | 2 H [ 0.5182847843 -0.0000000000 0.7721602685]
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248 | 3 H [ 0.5182847843 -0.0000000000 -0.7721602685]
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249 | }
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250 | )
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251 | Atomic Masses:
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252 | 15.99491 1.00783 1.00783
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253 |
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254 | SCF::compute: energy accuracy = 1.3900762e-07
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255 |
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256 | Initializing ShellExtent
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257 | nshell = 8
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258 | ncell = 29700
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259 | ave nsh/cell = 1.56034
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260 | max nsh/cell = 8
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261 | integral intermediate storage = 236328 bytes
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262 | integral cache = 7760632 bytes
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263 | nuclear repulsion energy = 8.9943855590
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264 |
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265 | Using symmetric orthogonalization.
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266 | n(SO): 10 1 3 5
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267 | Maximum orthogonalization residual = 4.62777
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268 | Minimum orthogonalization residual = 0.0230803
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269 | Total integration points = 4049
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270 | Integrated electron density error = -0.000073666823
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271 | iter 1 energy = -75.5855339144 delta = 2.14130e-01
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272 | Total integration points = 11317
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273 | Integrated electron density error = -0.000013302827
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274 | iter 2 energy = -75.5857388951 delta = 2.78603e-03
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275 | Total integration points = 11317
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276 | Integrated electron density error = -0.000013128717
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277 | iter 3 energy = -75.5856904889 delta = 1.77152e-03
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278 | Total integration points = 11317
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279 | Integrated electron density error = -0.000013251739
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280 | iter 4 energy = -75.5857933692 delta = 1.07119e-03
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281 | Total integration points = 11317
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282 | Integrated electron density error = -0.000013242665
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283 | iter 5 energy = -75.5857935857 delta = 5.31315e-05
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284 | Total integration points = 11317
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285 | Integrated electron density error = -0.000013243266
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286 | iter 6 energy = -75.5857935876 delta = 4.85993e-06
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287 | Total integration points = 11317
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288 | Integrated electron density error = -0.000013243260
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289 | iter 7 energy = -75.5857935876 delta = 1.42785e-07
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290 |
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291 | HOMO is 1 B1 = -0.194691
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292 | LUMO is 4 A1 = 0.064206
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293 |
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294 | total scf energy = -75.5857935876
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295 |
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296 | SCF::compute: gradient accuracy = 1.3900762e-05
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297 |
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298 | Initializing ShellExtent
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299 | nshell = 8
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300 | ncell = 29700
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301 | ave nsh/cell = 1.56034
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302 | max nsh/cell = 8
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303 | Total integration points = 11317
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304 | Integrated electron density error = -0.000013244740
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305 | Total Gradient:
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306 | 1 O 0.0003182616 -0.0000000000 -0.0000000001
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307 | 2 H -0.0001591308 0.0000000000 0.0015785174
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308 | 3 H -0.0001591308 0.0000000000 -0.0015785172
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309 |
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310 | Max Gradient : 0.0015785174 0.0001000000 no
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311 | Max Displacement : 0.0066683304 0.0001000000 no
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312 | Gradient*Displace: 0.0000225314 0.0001000000 yes
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313 |
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314 | taking step of size 0.009061
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315 |
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316 | CLKS: changing atomic coordinates:
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317 | Molecular formula: H2O
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318 | molecule<Molecule>: (
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319 | symmetry = c2v
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320 | symmetry_frame = [
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321 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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322 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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323 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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324 | unit = "angstrom"
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325 | { n atoms geometry }={
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326 | 1 O [ -0.0845909431 0.0000000000 0.0000000000]
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327 | 2 H [ 0.5191046377 -0.0000000000 0.7686315397]
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328 | 3 H [ 0.5191046377 -0.0000000000 -0.7686315397]
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329 | }
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330 | )
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331 | Atomic Masses:
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332 | 15.99491 1.00783 1.00783
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333 |
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334 | SCF::compute: energy accuracy = 2.5956611e-08
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335 |
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336 | Initializing ShellExtent
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337 | nshell = 8
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338 | ncell = 29700
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339 | ave nsh/cell = 1.56044
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340 | max nsh/cell = 8
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341 | integral intermediate storage = 236328 bytes
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342 | integral cache = 7760632 bytes
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343 | nuclear repulsion energy = 9.0071525117
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344 |
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345 | Using symmetric orthogonalization.
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346 | n(SO): 10 1 3 5
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347 | Maximum orthogonalization residual = 4.63241
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348 | Minimum orthogonalization residual = 0.0230296
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349 | Total integration points = 4049
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350 | Integrated electron density error = -0.000090402102
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351 | iter 1 energy = -75.5857316763 delta = 2.13759e-01
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352 | Total integration points = 11317
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353 | Integrated electron density error = -0.000016421510
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354 | iter 2 energy = -75.5858054755 delta = 5.13917e-04
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355 | Total integration points = 11317
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356 | Integrated electron density error = -0.000016420792
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357 | iter 3 energy = -75.5858055306 delta = 1.43121e-04
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358 | Total integration points = 11317
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359 | Integrated electron density error = -0.000016434619
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360 | iter 4 energy = -75.5858062179 delta = 1.12381e-04
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361 | Total integration points = 11317
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362 | Integrated electron density error = -0.000016429313
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363 | iter 5 energy = -75.5858062899 delta = 3.05897e-05
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364 | Total integration points = 11317
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365 | Integrated electron density error = -0.000016429463
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366 | iter 6 energy = -75.5858062901 delta = 1.26287e-06
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367 | Total integration points = 11317
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368 | Integrated electron density error = -0.000016429455
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369 | iter 7 energy = -75.5858062901 delta = 6.44890e-08
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370 |
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371 | HOMO is 1 B1 = -0.194953
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372 | LUMO is 4 A1 = 0.064492
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373 |
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374 | total scf energy = -75.5858062901
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375 |
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376 | SCF::compute: gradient accuracy = 2.5956611e-06
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377 |
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378 | Initializing ShellExtent
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379 | nshell = 8
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380 | ncell = 29700
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381 | ave nsh/cell = 1.56044
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382 | max nsh/cell = 8
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383 | Total integration points = 11317
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384 | Integrated electron density error = -0.000016430810
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385 | Total Gradient:
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386 | 1 O 0.0007372045 0.0000000000 0.0000000000
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387 | 2 H -0.0003686023 -0.0000000000 -0.0000414800
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388 | 3 H -0.0003686023 0.0000000000 0.0000414800
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389 |
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390 | Max Gradient : 0.0007372045 0.0001000000 no
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391 | Max Displacement : 0.0015228854 0.0001000000 no
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392 | Gradient*Displace: 0.0000015856 0.0001000000 yes
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393 |
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394 | taking step of size 0.002821
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395 |
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396 | CLKS: changing atomic coordinates:
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397 | Molecular formula: H2O
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398 | molecule<Molecule>: (
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399 | symmetry = c2v
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400 | symmetry_frame = [
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401 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
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402 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
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403 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
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404 | unit = "angstrom"
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405 | { n atoms geometry }={
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406 | 1 O [ -0.0853968195 0.0000000000 0.0000000000]
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407 | 2 H [ 0.5195075758 -0.0000000000 0.7680037107]
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408 | 3 H [ 0.5195075758 -0.0000000000 -0.7680037107]
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409 | }
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410 | )
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411 | Atomic Masses:
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412 | 15.99491 1.00783 1.00783
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413 |
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414 | SCF::compute: energy accuracy = 5.9359078e-09
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415 |
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416 | Initializing ShellExtent
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417 | nshell = 8
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418 | ncell = 29700
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419 | ave nsh/cell = 1.56047
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420 | max nsh/cell = 8
|
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421 | integral intermediate storage = 236328 bytes
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422 | integral cache = 7760632 bytes
|
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423 | nuclear repulsion energy = 9.0051846887
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424 |
|
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425 | Using symmetric orthogonalization.
|
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426 | n(SO): 10 1 3 5
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427 | Maximum orthogonalization residual = 4.6324
|
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428 | Minimum orthogonalization residual = 0.0230381
|
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429 | Total integration points = 4049
|
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430 | Integrated electron density error = -0.000091354899
|
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431 | iter 1 energy = -75.5857418056 delta = 2.13776e-01
|
---|
432 | Total integration points = 11317
|
---|
433 | Integrated electron density error = -0.000017014719
|
---|
434 | iter 2 energy = -75.5858070562 delta = 2.86401e-04
|
---|
435 | Total integration points = 11317
|
---|
436 | Integrated electron density error = -0.000017034395
|
---|
437 | iter 3 energy = -75.5858071050 delta = 8.44351e-05
|
---|
438 | Total integration points = 11317
|
---|
439 | Integrated electron density error = -0.000017029037
|
---|
440 | iter 4 energy = -75.5858072193 delta = 4.40697e-05
|
---|
441 | Total integration points = 11317
|
---|
442 | Integrated electron density error = -0.000017029957
|
---|
443 | iter 5 energy = -75.5858072262 delta = 9.31391e-06
|
---|
444 | Total integration points = 11317
|
---|
445 | Integrated electron density error = -0.000017030032
|
---|
446 | iter 6 energy = -75.5858072264 delta = 1.09688e-06
|
---|
447 | Total integration points = 11317
|
---|
448 | Integrated electron density error = -0.000017030023
|
---|
449 | iter 7 energy = -75.5858072264 delta = 1.29177e-07
|
---|
450 | Total integration points = 11317
|
---|
451 | Integrated electron density error = -0.000017030025
|
---|
452 | iter 8 energy = -75.5858072264 delta = 2.03986e-08
|
---|
453 |
|
---|
454 | HOMO is 1 B1 = -0.194985
|
---|
455 | LUMO is 4 A1 = 0.064382
|
---|
456 |
|
---|
457 | total scf energy = -75.5858072264
|
---|
458 |
|
---|
459 | SCF::compute: gradient accuracy = 5.9359078e-07
|
---|
460 |
|
---|
461 | Initializing ShellExtent
|
---|
462 | nshell = 8
|
---|
463 | ncell = 29700
|
---|
464 | ave nsh/cell = 1.56047
|
---|
465 | max nsh/cell = 8
|
---|
466 | Total integration points = 11317
|
---|
467 | Integrated electron density error = -0.000017030991
|
---|
468 | Total Gradient:
|
---|
469 | 1 O 0.0001979261 -0.0000000000 -0.0000000000
|
---|
470 | 2 H -0.0000989630 -0.0000000000 -0.0000698431
|
---|
471 | 3 H -0.0000989630 0.0000000000 0.0000698431
|
---|
472 |
|
---|
473 | Max Gradient : 0.0001979261 0.0001000000 no
|
---|
474 | Max Displacement : 0.0003479700 0.0001000000 no
|
---|
475 | Gradient*Displace: 0.0000000922 0.0001000000 yes
|
---|
476 |
|
---|
477 | taking step of size 0.000619
|
---|
478 |
|
---|
479 | CLKS: changing atomic coordinates:
|
---|
480 | Molecular formula: H2O
|
---|
481 | molecule<Molecule>: (
|
---|
482 | symmetry = c2v
|
---|
483 | symmetry_frame = [
|
---|
484 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
|
---|
485 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
|
---|
486 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
|
---|
487 | unit = "angstrom"
|
---|
488 | { n atoms geometry }={
|
---|
489 | 1 O [ -0.0855809572 0.0000000000 0.0000000000]
|
---|
490 | 2 H [ 0.5195996447 -0.0000000000 0.7679617079]
|
---|
491 | 3 H [ 0.5195996447 -0.0000000000 -0.7679617079]
|
---|
492 | }
|
---|
493 | )
|
---|
494 | Atomic Masses:
|
---|
495 | 15.99491 1.00783 1.00783
|
---|
496 |
|
---|
497 | SCF::compute: energy accuracy = 1.6761463e-09
|
---|
498 |
|
---|
499 | Initializing ShellExtent
|
---|
500 | nshell = 8
|
---|
501 | ncell = 29700
|
---|
502 | ave nsh/cell = 1.56051
|
---|
503 | max nsh/cell = 8
|
---|
504 | integral intermediate storage = 236328 bytes
|
---|
505 | integral cache = 7760632 bytes
|
---|
506 | nuclear repulsion energy = 9.0039817280
|
---|
507 |
|
---|
508 | Using symmetric orthogonalization.
|
---|
509 | n(SO): 10 1 3 5
|
---|
510 | Maximum orthogonalization residual = 4.63219
|
---|
511 | Minimum orthogonalization residual = 0.0230431
|
---|
512 | Total integration points = 4049
|
---|
513 | Integrated electron density error = -0.000090952623
|
---|
514 | iter 1 energy = -75.5857431083 delta = 2.13820e-01
|
---|
515 | Total integration points = 11317
|
---|
516 | Integrated electron density error = -0.000017069177
|
---|
517 | iter 2 energy = -75.5858071904 delta = 7.90372e-05
|
---|
518 | Total integration points = 11317
|
---|
519 | Integrated electron density error = -0.000017077580
|
---|
520 | iter 3 energy = -75.5858072669 delta = 2.67193e-05
|
---|
521 | Total integration points = 11317
|
---|
522 | Integrated electron density error = -0.000017080260
|
---|
523 | iter 4 energy = -75.5858072735 delta = 1.06559e-05
|
---|
524 | Total integration points = 11317
|
---|
525 | Integrated electron density error = -0.000017080515
|
---|
526 | iter 5 energy = -75.5858072736 delta = 1.03554e-06
|
---|
527 | Total integration points = 11317
|
---|
528 | Integrated electron density error = -0.000017080544
|
---|
529 | iter 6 energy = -75.5858072736 delta = 2.62445e-07
|
---|
530 | Total integration points = 11317
|
---|
531 | Integrated electron density error = -0.000017080522
|
---|
532 | iter 7 energy = -75.5858072736 delta = 1.48084e-07
|
---|
533 | Total integration points = 11317
|
---|
534 | Integrated electron density error = -0.000017080525
|
---|
535 | iter 8 energy = -75.5858072736 delta = 2.80704e-08
|
---|
536 |
|
---|
537 | HOMO is 1 B1 = -0.194983
|
---|
538 | LUMO is 4 A1 = 0.064334
|
---|
539 |
|
---|
540 | total scf energy = -75.5858072736
|
---|
541 |
|
---|
542 | SCF::compute: gradient accuracy = 1.6761463e-07
|
---|
543 |
|
---|
544 | Initializing ShellExtent
|
---|
545 | nshell = 8
|
---|
546 | ncell = 29700
|
---|
547 | ave nsh/cell = 1.56051
|
---|
548 | max nsh/cell = 8
|
---|
549 | Total integration points = 11317
|
---|
550 | Integrated electron density error = -0.000017080664
|
---|
551 | Total Gradient:
|
---|
552 | 1 O 0.0000062196 -0.0000000000 -0.0000000000
|
---|
553 | 2 H -0.0000031098 0.0000000000 -0.0000060255
|
---|
554 | 3 H -0.0000031098 -0.0000000000 0.0000060255
|
---|
555 |
|
---|
556 | Max Gradient : 0.0000062196 0.0001000000 yes
|
---|
557 | Max Displacement : 0.0000147693 0.0001000000 yes
|
---|
558 | Gradient*Displace: 0.0000000002 0.0001000000 yes
|
---|
559 |
|
---|
560 | All convergence criteria have been met.
|
---|
561 | The optimization has converged.
|
---|
562 |
|
---|
563 | Value of the MolecularEnergy: -75.5858072736
|
---|
564 |
|
---|
565 | Closed Shell Kohn-Sham (CLKS) Parameters:
|
---|
566 | Function Parameters:
|
---|
567 | value_accuracy = 2.091521e-10 (1.676146e-09) (computed)
|
---|
568 | gradient_accuracy = 2.091521e-08 (1.676146e-07) (computed)
|
---|
569 | hessian_accuracy = 0.000000e+00 (1.000000e-04)
|
---|
570 |
|
---|
571 | Molecular Coordinates:
|
---|
572 | IntMolecularCoor Parameters:
|
---|
573 | update_bmat = no
|
---|
574 | scale_bonds = 1
|
---|
575 | scale_bends = 1
|
---|
576 | scale_tors = 1
|
---|
577 | scale_outs = 1
|
---|
578 | symmetry_tolerance = 1.000000e-05
|
---|
579 | simple_tolerance = 1.000000e-03
|
---|
580 | coordinate_tolerance = 1.000000e-07
|
---|
581 | have_fixed_values = 0
|
---|
582 | max_update_steps = 100
|
---|
583 | max_update_disp = 0.500000
|
---|
584 | have_fixed_values = 0
|
---|
585 |
|
---|
586 | Molecular formula: H2O
|
---|
587 | molecule<Molecule>: (
|
---|
588 | symmetry = c2v
|
---|
589 | symmetry_frame = [
|
---|
590 | [ -0.0000000000000000 0.0000000000000000 1.0000000000000000]
|
---|
591 | [ 1.0000000000000000 0.0000000000000000 -0.0000000000000000]
|
---|
592 | [ -0.0000000000000000 1.0000000000000000 -0.0000000000000000]]
|
---|
593 | unit = "angstrom"
|
---|
594 | { n atoms geometry }={
|
---|
595 | 1 O [ -0.0855809572 0.0000000000 0.0000000000]
|
---|
596 | 2 H [ 0.5195996447 -0.0000000000 0.7679617079]
|
---|
597 | 3 H [ 0.5195996447 -0.0000000000 -0.7679617079]
|
---|
598 | }
|
---|
599 | )
|
---|
600 | Atomic Masses:
|
---|
601 | 15.99491 1.00783 1.00783
|
---|
602 |
|
---|
603 | Bonds:
|
---|
604 | STRE s1 0.97776 1 2 O-H
|
---|
605 | STRE s2 0.97776 1 3 O-H
|
---|
606 | Bends:
|
---|
607 | BEND b1 103.52132 2 1 3 H-O-H
|
---|
608 |
|
---|
609 | SymmMolecularCoor Parameters:
|
---|
610 | change_coordinates = no
|
---|
611 | transform_hessian = yes
|
---|
612 | max_kappa2 = 10.000000
|
---|
613 |
|
---|
614 | GaussianBasisSet:
|
---|
615 | nbasis = 19
|
---|
616 | nshell = 8
|
---|
617 | nprim = 19
|
---|
618 | name = "6-31G*"
|
---|
619 | Natural Population Analysis:
|
---|
620 | n atom charge ne(S) ne(P) ne(D)
|
---|
621 | 1 O -0.955667 3.774306 5.171036 0.010325
|
---|
622 | 2 H 0.477833 0.522167
|
---|
623 | 3 H 0.477833 0.522167
|
---|
624 |
|
---|
625 | SCF Parameters:
|
---|
626 | maxiter = 40
|
---|
627 | density_reset_frequency = 10
|
---|
628 | level_shift = 0.000000
|
---|
629 |
|
---|
630 | CLSCF Parameters:
|
---|
631 | charge = 0
|
---|
632 | ndocc = 5
|
---|
633 | docc = [ 3 0 1 1 ]
|
---|
634 |
|
---|
635 | Functional:
|
---|
636 | Standard Density Functional: XALPHA
|
---|
637 | Sum of Functionals:
|
---|
638 | +1.0000000000000000
|
---|
639 | XalphaFunctional: alpha = 0.70000000
|
---|
640 | Integrator:
|
---|
641 | RadialAngularIntegrator:
|
---|
642 | Pruned coarse grid employed
|
---|
643 | CPU Wall
|
---|
644 | mpqc: 7.94 9.02
|
---|
645 | NAO: 0.02 0.02
|
---|
646 | calc: 7.74 8.81
|
---|
647 | compute gradient: 2.89 3.32
|
---|
648 | nuc rep: 0.00 0.00
|
---|
649 | one electron gradient: 0.07 0.08
|
---|
650 | overlap gradient: 0.04 0.04
|
---|
651 | two electron gradient: 2.78 3.21
|
---|
652 | grad: 2.78 3.21
|
---|
653 | integrate: 1.48 1.88
|
---|
654 | two-body: 0.53 0.55
|
---|
655 | contribution: 0.11 0.14
|
---|
656 | start thread: 0.10 0.10
|
---|
657 | stop thread: 0.00 0.03
|
---|
658 | setup: 0.42 0.41
|
---|
659 | vector: 4.81 5.46
|
---|
660 | density: 0.01 0.02
|
---|
661 | evals: 0.05 0.04
|
---|
662 | extrap: 0.05 0.07
|
---|
663 | fock: 3.80 4.43
|
---|
664 | accum: 0.00 0.00
|
---|
665 | init pmax: 0.00 0.00
|
---|
666 | integrate: 3.19 3.79
|
---|
667 | local data: 0.01 0.00
|
---|
668 | setup: 0.11 0.10
|
---|
669 | start thread: 0.12 0.14
|
---|
670 | stop thread: 0.00 0.01
|
---|
671 | sum: 0.00 0.00
|
---|
672 | symm: 0.11 0.12
|
---|
673 | input: 0.18 0.19
|
---|
674 | vector: 0.03 0.04
|
---|
675 | density: 0.01 0.00
|
---|
676 | evals: 0.00 0.00
|
---|
677 | extrap: 0.00 0.01
|
---|
678 | fock: 0.02 0.02
|
---|
679 | accum: 0.00 0.00
|
---|
680 | ao_gmat: 0.01 0.01
|
---|
681 | start thread: 0.00 0.00
|
---|
682 | stop thread: 0.00 0.00
|
---|
683 | init pmax: 0.00 0.00
|
---|
684 | local data: 0.00 0.00
|
---|
685 | setup: 0.01 0.01
|
---|
686 | sum: 0.00 0.00
|
---|
687 | symm: 0.00 0.01
|
---|
688 |
|
---|
689 | End Time: Sat Apr 6 14:01:01 2002
|
---|
690 |
|
---|